Measuring of oxygen mass-transfer through the gas-liquid interface

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Authors

  • Erik Mölder Linnéuniversitetet
  • Aleksei Mashirin Linnéuniversitetet
  • Toomas Tenno Linnéuniversitetet

DOI:

https://doi.org/10.15626/Eco-Tech.2003.045

Keywords:

Liquid-gas interface; oxygen mass-transfer; overall transfer velocity.

Abstract

In the present study, oxygen mass-transfer processes through the liquid-air interface from
gas mixture with variable volume at constant pressure were investigated. This paper
describes a device based on the electrochemical oxygen sensor placed on the liquid-air
surface. The oxygen sensor measured the decrease of oxygen concentration in the small
volume under the device, that is in contact with deoxygenated liquid. Experimental data
obtained by the device were introduced to a novel mathematical model, which allowed
calculating diffusion flow through the liquid-air interface and diffusional conductivity P/1
of liquid surface.
By means of the developed device it is possible to measure the total impediment of the
air-water interface to oxygen mass-transfer.

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References

Adamson, A.W., 1997: Physical Chemistry of Surfaces. Wiley-Interscience Publication, New York.

Thibodeaux, L.J., 1966: Environmental Chemodynamics. Movement of Chemicals in Air, Water and Soil. 2nd ed. Wiley-Interscience Publication, New York.

Schwarzenbach, R.P., Gschwend, P.M., Imboden, D.M., 1993: Environmental Organic Chemistry. Wiley-Interscience Publication, New York.

Aratono, M., Kanda, T., Motomura, K., 1990: Study on the Adsorption and Micelle Formation of a Decylsulfinylethanol and Octysulfinylethanol Mixture. Langmuir 6, 843-846.

Rosen, M.J., Hua, X.Y. 1982: Surface Concentrations and Molecular Interactions in Binary Mixtures of Surfactants. J Colloid Interface Sci 86 Nol, 164-172. https://doi.org/10.1016/0021-9797(82)90052-2

Lucassen-Reynders, E.H., Lucassen, J., Giles, D., 1981: Surface and Bulk Properties of Mixed Anionic/Cationic Surfactant System J Colloid Interface Sci 81 Nol, 150-157. https://doi.org/10.1016/0021-9797(81)90312-X

Mölder, E., Tenno, T., Nigu, P., 1998: The Influence of Surfactants on Oxygen MassTransfer through the Air-Water Surface. Crit Rev Anal Chem 28-2, 75-80. https://doi.org/10.1080/10408349891194324

Molder, E., Tenno, T., Mashirin, A., 2002: The effect of surfactants on oxygen mass­transfer trough the air-water interface. Environmental Science and Pollution Research Special Issue 1, 39-42. https://doi.org/10.1007/BF02987424

Slevin, C.J., Ryley, S., Walton, D.J., Unwin, P.R., 1998: A New Approach for Measuring the Effect of a Monolayer on Molecular Transfer across an Air/Water

Interface Using Scanning Electrochemical Microscopy. Langmuir Vol 14, 19, 5331-5334. https://doi.org/10.1021/la980320k

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Published

2019-07-02